Axial chirality induction in flexible biphenols by hydrogen bonding and steric interactions

@article{Mizutani1997AxialCI,
  title={Axial chirality induction in flexible biphenols by hydrogen bonding and steric interactions},
  author={T. Mizutani and Hideki Takagi and O. Hara and T. Horiguchi and H. Ogoshi},
  journal={Tetrahedron Letters},
  year={1997},
  volume={38},
  pages={1991-1994}
}
Abstract Chiral induction in biphenols was studied as a model for intermolecular information transmission. Upon complexation with chiral trans -1,2-cyclohexanediamines (C 6 H 10 (NHR) 2 , R = H, CH 3 , CH 2 CH 2 Bu t ), axial chirality was induced in biphenols in toluene, CHCl 3 and THF. The induced chirality varies as the alkyl groups on the amino groups vary from H, CH 3 to CH 2 CH 2 Bu t . The bulky diamine (R = CH 2 CH 2 Bu t ) induced the opposite chirality to that induced by the less… Expand
Enantiomerization of Axially Chiral Biphenyls: Polarizable MD Simulations in Water and Butylmethylether
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