Autoxidation kinetics of aqueous nitric oxide.

Abstract

Reports on the kinetics of the autoxidation of aqueous nitric oxide are discussed. It is concluded that the correct rate law is -d[NO]/dt = 4kaq[NO]2[O2] with kaq = 2 x 10(6) M-2.s-1 at 25 degrees c and that a recent report of a rate law zero order in NO is incorrect.

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@article{Ford1993AutoxidationKO, title={Autoxidation kinetics of aqueous nitric oxide.}, author={Peter C Ford and David Anderson Wink and David M Stanbury}, journal={FEBS letters}, year={1993}, volume={326 1-3}, pages={1-3} }