Asymmetric methallylation of ketones catalyzed by a highly active organocatalyst 3,3'-F2-BINOL.

@article{Zhang2013AsymmetricMO,
  title={Asymmetric methallylation of ketones catalyzed by a highly active organocatalyst 3,3'-F2-BINOL.},
  author={Yongda Zhang and Ning Bo Li and Bo Qu and Shengli Ma and Heewon Lee and Nina C. Gonnella and Joe J. Gao and Wenjie Li and Zhulin Tan and Jonathan T Reeves and Jun Wang and Jon C. Lorenz and Guisheng Li and Diana C. Reeves and Ajith Premasiri and Nelu Grinberg and Nizar Haddad and Bruce Z. Lu and Jinhua J. Song and Chris Hugh Senanayake},
  journal={Organic letters},
  year={2013},
  volume={15 7},
  pages={
          1710-3
        }
}
(S)-3,3'-F2-BINOL has been synthesized for the first time and demonstrated as a highly active organocatalyst for asymmetric methallylation of ketones. Up to 98:2 enantioselectivity and 99% yield were obtained with 5 mol % catalyst loading. The catalyst (S)-3,3'-F2-BINOL could be easily recovered and reused. 
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TLDR
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