Asymmetric cobalt-catalyzed Diels-Alder reactions of a boron-functionalized 1,3-diene with alkynes and allylboration with aldehydes.

Abstract

[Structure: see text] A cobalt(I)-catalyzed Diels-Alder reaction of a 1-boron-functionalized 1,3-diene is the key step in a one-pot reaction interconnecting three simple starting materials to obtain a multifunctionalized product. This product incorporates a stereogenic quaternary center next to a stereogenic secondary alcohol functionality generated with a… (More)

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