Asymmetric Photocatalysis with Bis-cyclometalated Rhodium Complexes.

  title={Asymmetric Photocatalysis with Bis-cyclometalated Rhodium Complexes.},
  author={Xiaoqiang Huang and Eric Meggers},
  journal={Accounts of chemical research},
  volume={52 3},
Aspects of sustainability are playing an increasingly important role for the development of new synthetic methods. In this context, the combination of asymmetric catalysis, which is considered one of the most economic strategies to generate nonracemic chiral compounds, and visible light as an abundant source of energy to induce or activate chemical reactions has recently gained much attention. Furthermore, the combination of photochemistry with asymmetric catalysis provides new opportunity for… 

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