Association of Oxo-Molybdenum Dithiolene Complexes with a Multiamide Additive and Its Influence on the Ease of O-Atom Transfer.

Abstract

To regulate the reactivity of dithiolene dioxomolybdenum(VI) complexes, two systems were studied: (1) chelate recognition with a diamide additive, 1,3-bis(isobutyrylamino)benzene (1); (2) a dithiolene complex with four amide substituents, (n-Pr(4)N)(2)[Mo(IV)O{S(2)C(2)(CONH(2))(2)}(2)].0.5(i-PrOH).DMF (2) (S(2)C(2)(CONH(2))(2) = 1,2-dicarbamoylethylene-1,2… (More)

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