Aspartic acid side chain effect-experimental and theoretical insight.

@article{Roman2007AsparticAS,
  title={Aspartic acid side chain effect-experimental and theoretical insight.},
  author={Marko Ro{\vz}man},
  journal={Journal of the American Society for Mass Spectrometry},
  year={2007},
  volume={18 1},
  pages={121-7}
}
  • Marko Rožman
  • Published 2007 in
    Journal of the American Society for Mass…
Gas-phase H/D exchange and density functional theory study of the Asp and Glu side-chain carboxylic group intrinsic reactivity is reported. H/D exchange site specific treatment and some additional theoretical calculations showed that a side-chain carboxylic group may initiate proton transfer along with bond formation to one of its oxygens, i.e., possibility… CONTINUE READING