Arenethiolate Monolayer-Protected Gold Clusters

@inproceedings{Chen1999ArenethiolateMG,
  title={Arenethiolate Monolayer-Protected Gold Clusters},
  author={Shaowei Chen and Royce Wilton Murray},
  year={1999}
}
Nanometer-sized gold clusters stabilized by monolayers of arenethiolates prepared using the Brust reaction are somewhat larger (by TEM) and less thermally stable (by TGA) than those prepared under similar conditions and stabilized by alkanethiolates. Like the latter, the mean core size decreases for synthetic conditions based on larger thiol/Au ratios. The differential pulse voltammetry of the arenethiolates was especially interesting by displaying electrochemical ensemble Coulomb staircase… CONTINUE READING

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