Aqueous phase homogeneous catalysis using core–shell nanoreactors: Application to rhodium-catalyzed hydroformylation of 1-octene

Abstract

High catalytic activity (turnover frequencies up to 700 h) was achieved using new triphenylphosphinefunctionalized core cross-linked micelles, TPP@CCM, as nanoreactors and [Rh(acac)(CO)2] as catalyst precursor for the aqueous biphasic hydroformylation of 1-octene. While the hydrophobic core of the polymer offers an adequate environment for the catalytic… (More)

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Cite this paper

@inproceedings{Cardozo2017AqueousPH, title={Aqueous phase homogeneous catalysis using core–shell nanoreactors: Application to rhodium-catalyzed hydroformylation of 1-octene}, author={Andr{\'e}s Fernando Cardozo and Carine Julcour-Lebigue and Laurie Barthe and J Blanco and Si Chen and Florence Gayet and Eric Manoury and Xuewei Zhang and Muriel Lansalot and Bernadette Charleux and Carine Julcour and Franck D’Agosto and Rinaldo Poli and Henri Delmas}, year={2017} }