Aqueous biphasic hydroformylation in the presence of cyclodextrins mixtures: evidence of a positive synergistic effect.

Abstract

Mixtures of randomly methylated cyclodextrins of various sizes have been evaluated in the rhodium-catalysed hydroformylation of higher olefins in an aqueous biphasic medium. A marked positive non-linear effect on 1-tetradecene conversion is observed when the CD molar ratio in the mixture is modified. The formation of 2:1 ternary inclusion complexes between… (More)
DOI: 10.1039/c2dt30646h

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Cite this paper

@article{Ferreira2012AqueousBH, title={Aqueous biphasic hydroformylation in the presence of cyclodextrins mixtures: evidence of a positive synergistic effect.}, author={Michel Ferreira and François-Xavier Legrand and C{\'e}cile Machut and Herv{\'e} Bricout and S{\'e}bastien Tilloy and Eric Monflier}, journal={Dalton transactions}, year={2012}, volume={41 28}, pages={8643-7} }