Application of the Cell Method to the Statistical Thermodynamics of Solutions

@article{Prigogine1952ApplicationOT,
  title={Application of the Cell Method to the Statistical Thermodynamics of Solutions},
  author={I. Prigogine and V. Mathot},
  journal={Journal of Chemical Physics},
  year={1952},
  volume={20},
  pages={49-57}
}
  • I. Prigogine, V. Mathot
  • Published 1952
  • Physics
  • Journal of Chemical Physics
  • The cell method for pure liquids in the form used by Lennard‐Jones and Devonshire is extended to solutions. It is assumed that (a) the constituents are spherical in shape, with an isotropic field of force, (b) the distance of the maximum interaction for AA, BB, and AB pairs is about the same, and (c) there is random mixing.For the mean field in the ``cage,'' the complete 6–12 law, the harmonic oscillator, and the smoothed potential model have been studied. The smoothed potential model… CONTINUE READING
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