Application of multinuclear magnetic resonance and gauge-including projector-augmented-wave calculations to the study of solid group 13 chlorides.

@article{Chapman2009ApplicationOM,
  title={Application of multinuclear magnetic resonance and gauge-including projector-augmented-wave calculations to the study of solid group 13 chlorides.},
  author={Rebecca P. Chapman and David L Bryce},
  journal={Physical chemistry chemical physics : PCCP},
  year={2009},
  volume={11 32},
  pages={6987-98}
}
A series of four anhydrous group 13 chloride salts has been studied by (35/37)Cl solid-state NMR spectroscopy and complementary quantum chemical calculations. Due to the large (35/37)Cl quadrupolar interactions in these salts, a high magnetic field (21.1 T) and the variable-offset QCPMG technique was used to obtain full chlorine central transition (m = -1/2… CONTINUE READING