Application of linear solvation energy relationships to polymeric pseudostationary phases in micellar electrokinetic chromatography.

@article{Fujimoto2001ApplicationOL,
  title={Application of linear solvation energy relationships to polymeric pseudostationary phases in micellar electrokinetic chromatography.},
  author={Chihiro Fujimoto},
  journal={Electrophoresis},
  year={2001},
  volume={22 7},
  pages={
          1322-9
        }
}
Polymerized sodium 11-acrylamidoundecanoate (poly(Na 11-AAU)) was used as a pseudostationary phase (PSP) for micellar electrokinetic chromatography to separate uncharged compounds. The polymer PSP showed signifcantly different solute migration behaviors from conventional micelles including sodium dodecyl sulfate and poly (sodium 10-undecylenate), giving high separation efficiencies (>200000 theoretical plates/m). Linear solvation energy relationships were used to evaluate and characterize the… CONTINUE READING
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