Antimony-Supported Cu4I4 Cuboid with Short Cu-Cu Bonds: Structural Premise for Near-Infrared Thermoluminescence.


Herein we report the synthesis, temperature-dependent X-ray structures (100, 150, 200, 250, 273, and 300 K), and solid-state emissive properties of the antimony-copper(I)-iodo cluster [Cu4(I)4(Sb(i)Pr3)4] (1), supported by the trialkylantimony donor Sb(i)Pr3. Overall, 1 exhibits a distorted cuboidal structure, wherein a twisting of the "cube" generates an… (More)
DOI: 10.1021/acs.inorgchem.5b02933


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