Anti-Markovnikov hydroimination of terminal alkynes in gold-catalyzed pyridine construction from ammonia.

Abstract

Gold-catalyzed hydroimination of terminal alkynes, giving rise to anti-Markovnikov adducts concomitant with unstable Markovnikov adducts is described. The elementary step can be applied for the construction of pyridine derivatives from ammonia and alkynes.

DOI: 10.1039/c5cc04091d

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Cite this paper

@article{Wang2015AntiMarkovnikovHO, title={Anti-Markovnikov hydroimination of terminal alkynes in gold-catalyzed pyridine construction from ammonia.}, author={Liliang Wang and Lingbing Kong and Yongxin Li and Rakesh Ganguly and Rei Kinjo}, journal={Chemical communications}, year={2015}, volume={51 62}, pages={12419-22} }