Antenna effect by organometallic chromophores in bimetallic d-f complexes.

@article{Ferraro2013AntennaEB,
  title={Antenna effect by organometallic chromophores in bimetallic d-f complexes.},
  author={Franklin Ferraro and Day{\'a}n P{\'a}ez-Hern{\'a}ndez and Juliana A Murillo-L{\'o}pez and Alvaro Mu{\~n}oz-Castro and Ramiro Arratia-P{\'e}rez},
  journal={The journal of physical chemistry. A},
  year={2013},
  volume={117 33},
  pages={7847-54}
}
The nature of the intermetallic bond in a series of complexes of the type [Cp2-TM-M-Cp2] (where TM = Re and M = Y, La, Lu, Yb, Ac; also TM = Os and M = Th; Cp = cyclopentadienyl ligand) have been studied by relativistic two-component density functional theory (DFT) calculations. The results obtained in this work show that the interaction between the… CONTINUE READING