Anomeric configuration, glycosidic linkage, and the solution conformational entropy of O-linked disaccharides.

Abstract

Oligosaccharides perform a large number of biological roles, as dictated by their chemical structure and spatial arrangement. While conformational entropies are usually determined in vacuo by computer modeling, molecular recognition processes normally take place in solution. Here I show results of experiments using size-exclusion chromatography (SEC), an… (More)

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