Analytical modeling of micelle growth. 2. Molecular thermodynamics of mixed aggregates and scission energy in wormlike micelles.

@article{Danov2019AnalyticalMO,
  title={Analytical modeling of micelle growth. 2. Molecular thermodynamics of mixed aggregates and scission energy in wormlike micelles.},
  author={Krassimir D. Danov and Peter A. Kralchevsky and Simeon D. Stoyanov and Joanne L. Cook and Ian Stott},
  journal={Journal of colloid and interface science},
  year={2019},
  volume={551},
  pages={
          227-241
        }
}
View on PubMed
arxiv.org
14 Citations
Background Citations
3

Figures and Tables from this paper

14 Citations

Citation Type

Citation Type

Analytical modeling of micelle growth. 1. Chain-conformation free energy of binary mixed spherical, wormlike and lamellar micelles.
Analytical modeling of micelle growth. 4. Molecular thermodynamics of wormlike micelles from ionic surfactants: Theory vs. experiment.
Analytical modeling of micelle growth. 3. Electrostatic free energy of ionic wormlike micelles - Effects of activity coefficients and spatially confined electric double layers.
Scission energies of surfactant wormlike micelles loaded with nonpolar additives.
Towards a general understanding of the effects of hydrophobic additives on the viscosity of surfactant solutions
Rheology of mixed solutions of sulfonated methyl esters and betaine in relation to the growth of giant micelles and shampoo applications.
Model predictive control for wormlike micelles (WLMs): Application to a system of CTAB and NaCl
Salt- and pH-Dependent Viscosity of SDS/LAPB Solutions: Experiments and a Semiempirical Thermodynamic Model.
TLDR
Novel data is presented on the composition-, pH-, and salt-dependent zero shear viscosity of the commercially important mixture of anionic sodium dodecyl sulfate and zwitterionic lauramidopropyl betaine and how the pKa shift from NMR experiments can be used to parameterize the thermodynamic model is used.
A General Approach to Describing Fast Relaxation with Regard to Specific Features of Micellar Models
It has been shown that, when passing from the Becker–Döring finite-difference equations to the differential kinetic equation for the function of aggregate distribution over aggregation numbers, the…
Liquid/liquid interface in periodic boundary condition.
TLDR
Without any curvature effect on surface tension, planar (slab), cylindrical, and spherical structures are successively obtained as a function of the total composition and elongation of the box, in accordance with molecular dynamics simulations for a water/heptane system.
...
...

References

SHOWING 1-10 OF 78 REFERENCES
Analytical modeling of micelle growth. 1. Chain-conformation free energy of binary mixed spherical, wormlike and lamellar micelles.
Growth of wormlike micelles in nonionic surfactant solutions: Quantitative theory vs. experiment.
Micelle-monomer equilibria in solutions of ionic surfactants and in ionic-nonionic mixtures: a generalized phase separation model.
Theory of surfactant self-assembly : a predictive molecular thermodynamic approach
A thermodynamic treatment of surfactant self-assembly in aqueous media is developed that allows an a priori quantitative prediction of the aggregation behavior of surfactants, starting from their…
Effect of Counterion Binding on Micellar Solution Behavior: 1. Molecular−Thermodynamic Theory of Micellization of Ionic Surfactants
A molecular−thermodynamic theory is developed to model the micellization of ionic surfactants with added electrolytes in aqueous solution, by combining a thermodynamic description of the micellar…
Thermodynamics of mixed micellization. Pseudo-phase separation models
The authors present a general model of micellization of binary nonionic and binary ionic surfactant mixtures in dilute solution. For the latter they use the parameter ..beta.. to describe the…
Disclike vs. cylindrical micelles: generalized model of micelle growth and data interpretation.
Kinetics of micellisation and relaxation of cylindrical micelles described by the difference Becker-Döring equation.
TLDR
A comparison of the computed results with the analytical ones known from solutions of the linearized and nonlinearized differential Becker-Döring kinetic equations demonstrates a general agreement at higher concentrations of the surfactant above the critical micellar concentration.
Growth of Giant Rodlike Micelles of Ionic Surfactant in the Presence of Al3+ Counterions
TLDR
The model of micelle growth, extended in this way, compared well with the experimental data and provides a quantitative description of the micelle size and charge as functions of the surfactant.
Mixed Micelle Solutions
Aqueous solutions of two surfactants exhibit striking alterations in physical properties such as surface tension and intensity of scattered light which can be associated with the formation of…
...
...