Analysis of the bromate-sulfite-ferrocyanide pH oscillator using the particle filter: toward the automated modeling of complex chemical systems.


This study was aimed at identifying a quantitatively accurate reaction model of the bromate-sulfilte-ferrocyanide (BSF) pH oscillator by using the simulation-based model estimation algorithm known as the particle filter. The Rbai-Kaminaga-Hanazaki (RKH) model proposed for the BSF system was extended by adding the protonation equilibrium of SO42-, for which… (More)
DOI: 10.1021/jp106700f

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