An unusual nitrogenous terphenyl derivative from fruiting bodies of the basidiomycete Sarcodon leucopus.

@article{Geraci2000AnUN,
  title={An unusual nitrogenous terphenyl derivative from fruiting bodies of the basidiomycete Sarcodon leucopus.},
  author={C Geraci and Placido Neri and Caroline Paterno and Claudia Rocco and Cristina Tringali},
  journal={Journal of natural products},
  year={2000},
  volume={63 3},
  pages={347-51}
}
A new nitrogenous metabolite with a p-terphenyl core, sarcodonin (3), has been isolated from fruiting bodies of the basidiomycete Sarcodon leucopus. The structure of 3 was determined through a careful study of its peracetate 4, by use of an array of spectroscopic techniques (including (15)N NMR, gradient-enhanced, and reverse-detected 2D NMR experiments) and chemical degradation. ROESY data and molecular mechanics (MM+) calculations led to assignment of the absolute configuration of 4. Compound… CONTINUE READING

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