An unexpected role of a trace amount of water in catalyzing proton transfer in phosphine-catalyzed (3 + 2) cycloaddition of allenoates and alkenes.

Abstract

Beijing National Laboratory for Molecular Sciences (BNLMS), Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking UniVersity, Beijing 100871, China, Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining 810008, China, and Key Laboratory of Organic Synthesis of Jiangsu ProVince… (More)

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