An ortho-palladated dimethylbenzylamine complex as a highly efficient turnover catalyst for the decomposition of P=S insecticides. Mechanistic studies of the methanolysis of some P=S-containing phosphorothioate triesters.

@article{Lu2005AnOD,
  title={An ortho-palladated dimethylbenzylamine complex as a highly efficient turnover catalyst for the decomposition of P=S insecticides. Mechanistic studies of the methanolysis of some P=S-containing phosphorothioate triesters.},
  author={Zhong-lin Lu and A. A. Neverov and R. Brown},
  journal={Organic \& biomolecular chemistry},
  year={2005},
  volume={3 18},
  pages={
          3379-87
        }
}
An ortho-palladated complex Pd(dmba)(py)(OTf) (9), or Pd(N,N-dimethylbenzylamine)(pyridine)(trifluoromethanesulfonate), was synthesized and its solution properties in methanol studied as a function of pH. In neutral solution the triflate dissociates from the complex to give a dominant form Pd(dmba)(py)(HOCH3), and in acid the pyridine dissociates to give Pyr-H+ and Pd(dmba)(HOCH3)(HOCH3). Under basic conditions, Pd(dmba)(py)(HOCH3) ionizes to give Pd(dmba)(py)(-OCH3) from which the pyridine can… Expand
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Hydrolysis of 4-nitro- and 2,4-dinitro-phenyl carboxylates proceeds catalytically in the presence of ortho-palladated aryl oximes 4. The catalytic reaction involves two active species, identified asExpand
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