An organic hydride transfer reaction of a ruthenium NAD model complex leading to carbon dioxide reduction.

@article{Ohtsu2012AnOH,
  title={An organic hydride transfer reaction of a ruthenium NAD model complex leading to carbon dioxide reduction.},
  author={Hideki Ohtsu and Koji Tanaka},
  journal={Angewandte Chemie},
  year={2012},
  volume={51 39},
  pages={
          9792-5
        }
}
Ruthenium will fix it: CO(2) undergoes reduction to HCO(2)(-) when placed over a solution of a ruthenium complex bearing an NADH model ligand 1 (black in right structural formula). The organic hydride transfer is triggered by the addition of benzoate anion, which rapidly forms a complex with 1, a complex that is a stronger reductant than 1. A photocatalytic variant of the reaction using triethanolamine as a sacrificial reagent has also been developed. 
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