An optically active chromium(0)-complexed benzaldehyde in organic synthesis: A highly stereocontrolled asymmetric synthesis of (2R,3S)-(-)-N-benzoyl-3-phenylisoserine methyl ester, the taxol C-13 side chain analogue

@article{Mukai1992AnOA,
  title={An optically active chromium(0)-complexed benzaldehyde in organic synthesis: A highly stereocontrolled asymmetric synthesis of (2R,3S)-(-)-N-benzoyl-3-phenylisoserine methyl ester, the taxol C-13 side chain analogue},
  author={C. Mukai and I. J. Kim and M. Hanaoka},
  journal={Tetrahedron-asymmetry},
  year={1992},
  volume={3},
  pages={1007-1010}
}
Abstract An asymmetric aldol reaction of (+)-chromium(0)-complexed benzaldehyde 4 with the titanium enolate generated from the ethanethioate 5 provided the anti -aldol product 6 in a highly stereoselective manner, which was subsequently converted to the taxol C-13 side chain. 
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