An insight into the communication between β-olefin/phenyl olefin-mediated acceptors and porphyrin π-system: a way to establish porphyrin based chemodosimeters and chemosensors.

@article{Chahal2017AnII,
  title={An insight into the communication between β-olefin/phenyl olefin-mediated acceptors and porphyrin π-system: a way to establish porphyrin based chemodosimeters and chemosensors.},
  author={Mandeep Chahal and Muniappan Sankar and Raymond John Butcher},
  journal={Physical chemistry chemical physics : PCCP},
  year={2017},
  volume={19 6},
  pages={4530-4540}
}
The synthesis of three new classes of mixed β-pyrrole substituted tetraphenylporphyrins, MTPP(R), MTPP(Br)2(R) (where R = -CH[double bond, length as m-dash]C(CN)2, -CH[double bond, length as m-dash]C(CN)(COOC2H5), -CH[double bond, length as m-dash](CN)(COOH) and M = 2H, Ni(ii), Cu(ii)) and MTPP(NO2)(Ph-p-R')2 (R' = -CHO and -CH[double bond, length as m-dash]C(CN)2 and M = 2H, Ni(ii), Cu(ii)) have been reported. The crystal structures of CuTPP(Br)2-ECA (7a), NiTPP(NO2)(Ph-p-CHO)2 (9) and NiTPP… CONTINUE READING