An improvement in the bending ability of a hinged trisaccharide with the assistance of a sugar-sugar interaction.

Abstract

Hinged di- and trisaccharides incorporating 2,4-diamino-beta-D-xylopyranoside as a hinge unit (Hin) were synthesized. Bridging of the diamino group of Hin by carbonylation or chelation to a metal ion results in a conformational change from (4)C1 to (1)C4, which in turn causes a bending of the oligosaccharides. In this study, the bending abilities of the… (More)

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Cite this paper

@article{Yuasa2005AnII, title={An improvement in the bending ability of a hinged trisaccharide with the assistance of a sugar-sugar interaction.}, author={Hideya Yuasa and Takuhiro Izumi and Nobuyuki Mitsuhashi and Yasuhiro Kajihara and H. Hashimoto}, journal={Chemistry}, year={2005}, volume={11 22}, pages={6478-90} }