An electron paramagnetic resonance study of nitrogen dioxide dissolved in water, carbon tetrachloride and some organic compounds

@article{Mendiara2001AnEP,
  title={An electron paramagnetic resonance study of nitrogen dioxide dissolved in water, carbon tetrachloride and some organic compounds},
  author={Sara Noem{\'i} Mendiara and A. Sagedahl and Luis Jos{\'e} Perissinotti},
  journal={Applied Magnetic Resonance},
  year={2001},
  volume={20},
  pages={275-287}
}
Electron paramagnetic resonance spectrometry was used to characterize and measure the concentration of nitrogen dioxide dissolved in water, carbon tetrachloride, n-hexane, acetone and benzene at 290 K. Solutions were monitored by ultraviolet spectrometry. We measured the equilibrium constant for N2O4 plus NO2 dissolved in n-hexane and carbon tetrachloride. In order to investigate the formation of organic nitroxide type intermediates, some experiments were designed to examine the role of NO and… 

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