An adiabatic model for calculating overtone spectra of dimers such as (H(2)O)(2).


The near-infrared and visible wavelength spectrum of the water dimer is considered to be the major contributor to the so-called water continuum at these wavelengths. However, theoretical models of this spectrum require the simultaneous treatment of both monomer and dimer excitations. A model for treating this problem is proposed which is based upon a Franck… (More)
DOI: 10.1098/rsta.2011.0243


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