An Investigation of the Symmetric and Asymmetric Cleavage Products in the System Aluminum Trihalide/1-Butylimidazole.

Abstract

Mixtures of AlX3 (X=Cl, Br) with 1-butylimidazole (BuIm) in various ratios were investigated. The mixtures were characterized by multinuclear (1 H, 27 Al, 13 C, and 15 N) NMR, IR, and Raman spectroscopy and in part by single-crystal X-ray diffraction. Depending on the molar fraction x(AlBr3 ) of the AlBr3 -based mixtures, the cationic aluminum complexes [Al… (More)
DOI: 10.1002/chem.201701553

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