Aminoalkyl radicals: direct observation and reactivity toward oxygen, 2,2,6,6-tetramethylpiperidine-N-oxyl, and methyl acrylate.

@article{Laleve2007AminoalkylRD,
  title={Aminoalkyl radicals: direct observation and reactivity toward oxygen, 2,2,6,6-tetramethylpiperidine-N-oxyl, and methyl acrylate.},
  author={Jacques Lalev{\'e}e and Bernadette Graff and Xavier Allonas and J. P. Fouassier},
  journal={The journal of physical chemistry. A},
  year={2007},
  volume={111 30},
  pages={
          6991-8
        }
}
The reactivity of 11 aminoalkyl radicals toward different additives [oxygen, 2,2,6,6-tetramethylpiperidine-N-oxyl (TEMPO), and methyl acrylate (MA)] has been investigated through laser flash photolysis and quantum mechanical calculations. The transient absorption spectra of the radicals were recorded: good agreement was found with the spectra calculated by using quantum mechanical calculations. All the interaction rate constants were measured. A large range of values are obtained: (0.04-3) x 10… CONTINUE READING

From This Paper

Topics from this paper.

Citations

Publications citing this paper.
Showing 1-10 of 10 extracted citations