Allene Oxide Synthase Pathway in Cereal Roots: Detection of Novel Oxylipin Graminoxins

@article{Grechkin2018AlleneOS,
  title={Allene Oxide Synthase Pathway in Cereal Roots: Detection of Novel Oxylipin Graminoxins},
  author={Alexander N Grechkin and Anna V. Ogorodnikova and A. M. Egorova and Fakhima K. Mukhitova and Tatiana M Ilyina and Bulat I. Khairutdinov},
  journal={ChemistryOpen},
  year={2018},
  volume={7},
  pages={336 - 343}
}
Abstract Young roots of wheat, barley, and sorghum, as well as methyl jasmonate pretreated rice seedlings, undergo an unprecedented allene oxide synthase pathway targeted to previously unknown oxylipins 1–3. These Favorskii‐type products, (4Z)‐2‐pentyl‐4‐tridecene‐1,13‐dioic acid (1), (2′Z)‐2‐(2′‐octenyl)‐decane‐1,10‐dioic acid (2), and (2′Z,5′Z)‐2‐(2′,5′‐octadienyl)‐decane‐1,10‐dioic acid (3), have a carboxy function at the side chain, as revealed by their MS and NMR spectral data. Compounds 1… 
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