Alkali metal cation interactions with 15-crown-5 in the gas phase: revisited.


Quantitative interactions of the alkali metal cations with the cyclic 15-crown-5 polyether ligand (15C5) are studied. In this work, Rb(+)(15C5) and Cs(+)(15C5) complexes are formed using electrospray ionization and studied using threshold collision-induced dissociation with xenon in a guided ion beam tandem mass spectrometer. The energy-dependent cross… (More)
DOI: 10.1021/jp4116172


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