Corpus ID: 118345693

Algebraic Determination of Spectral Characteristics of Rovibrational States of Diatomic Molecules. II. Analysis of the Vibration-Rotation Interaction by Means of the Factorization Method

@article{Astashkevich2011AlgebraicDO,
  title={Algebraic Determination of Spectral Characteristics of Rovibrational States of Diatomic Molecules. II. Analysis of the Vibration-Rotation Interaction by Means of the Factorization Method},
  author={Sergey A. Astashkevich},
  journal={arXiv: Atomic Physics},
  year={2011}
}
An algebraic model taking into account the influence of the molecular rotation on the wave functions of vibrational-rotational states of the diatomic molecule using the formalism of the ladder operators and an expansion in a small parameter characterizing the vibrational-rotational interaction have been proposed for the potentials whose the creation and annihilation operators can be constructed. Expressions for the expansion of the wave function of the vibrational-rotational states in a set of… Expand

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