Aggregation Processes of Perylene Bisimide Diimidazolium Salts.

@article{DAnna2015AggregationPO,
  title={Aggregation Processes of Perylene Bisimide Diimidazolium Salts.},
  author={Francesca D'Anna and Salvatore Marullo and Giuseppe Lazzara and Paola Vitale and Renato Noto},
  journal={Chemistry},
  year={2015},
  volume={21 42},
  pages={14780-90}
}
The supramolecular aggregation of three diimidazolium-functionalized perylene bisimides, differing in the alkyl chain length was investigated. These salts form aggregates in solvents like chloroform, dichloromethane, and glycerol. Solvent-, concentration-, and temperature-dependent spectroscopic studies were carried out, evidencing the occurrence of an isodesmic, enthalpy-driven aggregation process, underpinned by π-π stacking and hydrogen bonding. Moreover, dynamic light scattering (DLS… CONTINUE READING