Aggregates of a cationic porphyrin as supramolecular probes for biopolymers.

Abstract

The copper(II) derivative of the dicationic trans-bis(N-methylpyridinium-4-yl)diphenylporphyrin (t-CuPagg) forms large fractal aggregates in aqueous solution under moderate ionic strength conditions. A kinetic investigation of the aggregation process allows for a choice of experimental conditions to quickly obtain stable assemblies in solution. These… (More)
DOI: 10.1016/j.jinorgbio.2015.09.013

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