After 200 years: the structure of bleach and characterization of hypohalite ions by single-crystal X-ray diffraction.

  title={After 200 years: the structure of bleach and characterization of hypohalite ions by single-crystal X-ray diffraction.},
  author={Filip Topi{\'c} and Joseph M. Marrett and Tristan H. Borchers and Hatem M. Titi and Christopher J. Barrett and Tomislav Fri{\vs}{\vc}i{\'c}},
  journal={Angewandte Chemie},
We report the first X-ray single crystal structures of hypochlorite (ClO - ) and hypobromite (BrO - ) salts, including hydrated sodium hypochlorite - a staple of the chlorine industry and ubiquitous bleaching and disinfection agent for almost 200 years. The structures, supported by variable-temperature Raman spectroscopy on individual crystals and periodic density-functional theory (DFT) calculations, provide insight into solid-state geometry and supramolecular chemistry of hypohalite ions. 



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  • C. BunnL. ClarkI. Clifford
  • Materials Science
    Proceedings of the Royal Society of London. Series A - Mathematical and Physical Sciences
  • 1935
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