Affinity capillary electrophoresis: the theory of electromigration

  title={Affinity capillary electrophoresis: the theory of electromigration},
  author={Pavel Dubsk{\'y} and Martin Dvoř{\'a}k and Martin Ansorge},
  journal={Analytical and Bioanalytical Chemistry},
AbstractWe focus on the state-of-the-art theory of electromigration under single and multiple complexation equilibrium. Only 1:1 complexation stoichiometry is discussed because of its unique status in the field of affinity capillary electrophoresis (ACE). First, we summarize the formulas for the effective mobility in various ACE systems as they appeared since the pioneering days in 1992 up to the most recent theories till 2015. Disturbing phenomena that do not alter the mobility of the analyte… 

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