Adsorptive removal of dibenzothiophene from model fuels over one-pot synthesized PTA@MIL-101(Cr) hybrid material.

@article{Jia2013AdsorptiveRO,
  title={Adsorptive removal of dibenzothiophene from model fuels over one-pot synthesized PTA@MIL-101(Cr) hybrid material.},
  author={Shaoyi Jia and Yan-Fei Zhang and Y. Liu and F. Qin and Haitao Ren and Songhai Wu},
  journal={Journal of hazardous materials},
  year={2013},
  volume={262},
  pages={
          589-97
        }
}
Hybrid nanomaterials comprising phosphotungstic acid (PTA) and MIL-101(Cr) were prepared through one-pot synthesis and post-modification methods and then were used as adsorbents of dibenzothiophene (DBT) from simulated diesel fuels. Samples obtained by different ways (encapsulation and impregnation) were characterized by nitrogen adsorption, transmission electron microscope (TEM), X-ray diffraction (XRD), Fourier transform infrared spectrum (FT-IR) and series of adsorption experiments. The… Expand
View on PubMed
doi.org
45 Citations
Highly Influential Citations
2
Background Citations
1
Methods Citations
1

45 Citations

Citation Type

Citation Type

Synthesis and adsorption performance of a modified micro-mesoporous MIL-101(Cr) for VOCs removal at ambient conditions
Abstract In this study, dynamic adsorption behavior of different gaseous volatile organic compounds (VOCs) on a new modified M-MIL-101(Cr) was investigated with a great emphasis on gasoline… Expand
BN/ZIF-8 derived carbon hybrid materials for adsorptive desulfurization: Insights into adsorptive property and reaction kinetics
Abstract Adsorption of stubborn sulfides from fuels is a feasible desulfurization strategy to obtain clean fuels, however, the exploration of efficient adsorbents to achieve this target remains a… Expand
(Zn, Ni, Cu)-BTC Functionalized with Phosphotungstic Acid for Adsorptive Desulfurization in the Presence of Benzene and Ketone
A novel composite adsorbent, PTA@(Zn, Ni, Cu)-BTC, was prepared by (Zn, Ni, Cu)-BTC doped with different amounts of phosphotungstic acid (PTA) using an impregnation method. Apparatus like nitrogen… Expand
An efficient route from reproducible glucose to 5-hydroxymethylfurfural catalyzed by porous coordination polymer heterogeneous catalysts
Abstract Novel porous coordination polymers (PCPs) modified with sulfonic acid/phosphotungstic acid (PTA) were prepared by hydrothermal method via one-pot self-assembly. The materials were… Expand
Enhanced adsorption of thiophene with the GO-modified bimetallic organic framework Ni-MOF-199
Abstract A new type of metal organic framework GO/Ni-MOF-199 was synthesized using the solvothermal method in combination with different amounts of graphene oxide (0%, 0.5%, 1.75% and 5%) in order to… Expand
Highly efficient simultaneous ultrasonic-assisted adsorption of methylene blue and rhodamine B onto metal organic framework MIL-68(Al): central composite design optimization
In the present work, metal organic framework MIL-68 (MIL = Material of Institute Lavoisier), with metal sites of aluminum ions (namely MIL-68(Al)), was synthesized by a simple, fast and low-cost… Expand
Synthesis of novel and engineered UiO-66/graphene oxide nanocomposite with enhanced H2S adsorption capacity
Abstract Herein, in order to desulfurize the gas streams and assist in the environmental protection, a novel nanocomposite adsorbent was synthesized. To this end, the Zr-metal organic framework… Expand
Metal‐organic frameworks for highly efficient adsorption of dibenzothiophene from liquid fuels
By taking desulfurization of liquid fuels as a demonstrative example, a bottom-up selection was performed to find the metal-organic frameworks (MOF)-type adsorbents with highly efficient adsorption… Expand
High organic sulfur removal performance of a cobalt based metal-organic framework.
TLDR
Maximum efficiency and reusability in DBT removal occur under the mild reaction conditions, and the selectivity test of DBT over naphthalene (NA) clearly shows that π-π interactions between organic linkers of TMU-11 and the aromatic ring of D BT are not responsible for the adsorption desulfurization process. Expand
Efficient adsorptive removal of dibenzothiophene from model fuel over heteroatom-doped porous carbons by carbonization of an organic salt
Abstract A series of oxygen and nitrogen-doped porous carbons were synthesized by carbonization of tetrasodium ethylenediamine tetraacetic acid (EDTA-4Na) at various temperatures. Due to the high… Expand
...
1
2
3
4
5
...

References

SHOWING 1-10 OF 47 REFERENCES
Chromium(III) Terephthalate Metal Organic Framework (MIL-101): HF-Free Synthesis, Structure, Polyoxometalate Composites, and Catalytic Properties
Hybrid materials of the metal–organic framework (MOF), chromium(III) terephthalate (MIL-101), and phosphotungstic acid (PTA) were synthesized in aqueous media in the absence of hydrofluoric acid. XRD… Expand
Hybrid polyoxotungstate/MIL-101 materials: synthesis, characterization, and catalysis of H2O2-based alkene epoxidation.
TLDR
The hybrid PW(x)/MIL-101 materials were stable to leaching, behaved as true heterogeneous catalysts, were easily recovered by filtration, and reused several times with the maintenance of the catalytic performance. Expand
Adsorption of Dibenzothiophenes on Nanoporous Carbons: Identification of Specific Adsorption Sites Governing Capacity and Selectivity†
Adsorption of dibenzothiophene (DBT) and 4,6-dimethyldibenzothiophene (4,6-DMDBT) from simulated diesel fuel with 20 ppmw total concentration of sulfur was investigated on polymer-derived carbon and… Expand
Highly dispersed platinum in metal organic framework NH2-MIL-101(Al) containing phosphotungstic acid – Characterization and catalytic performance
Abstract The synthesis, characterization (FT-IR, XPS, NMR, UV–Vis), and catalytic performance of Pt supported on phosphotungstic acid (PTA) encapsulated in a metal organic framework (MOF) are… Expand
Building MOF bottles around phosphotungstic acid ships: One-pot synthesis of bi-functional polyoxometalate-MIL-101 catalysts
Abstract A new strategy has been developed for the direct encapsulation of polyoxometalates (POMs) into MIL-101(Cr). The addition of phosphotungstic acid (PTA) to the synthesis mixture of MIL-101… Expand
Selective adsorption of dibenzothiophene by functionalized metal organic framework sorbents
Abstract The adsorption of organosulfur compounds directly from liquid fuels has potential advantages over hydrodesulfurization processes including higher efficiencies and lower costs. A series of… Expand
Comparative study of hydrogen sulfide adsorption in the MIL-53(Al, Cr, Fe), MIL-47(V), MIL-100(Cr), and MIL-101(Cr) metal-organic frameworks at room temperature.
TLDR
Hydrogen sulfide gravimetric isotherm adsorption measurements highlighted the regenerability of MIL-53(Al, Cr, Fe) and MIL-47(V) MOFs after H(2)S treatment, whereas MIL-100 and Mil-101 CH(4) advertisersorption capacities were significantly decreased. Expand
Thermal regeneration of the metal organic frameworks used in the adsorption of refractory organosulfur compounds from liquid fuels
Abstract The Metal Organic Framework (MOF) C300 system was used as a sorbent of benzothiophene (BT), dibenzothiophene (DBT) and 4,6-dimethyldibenzothiophene (DMDBT) from simulated diesel fuel at… Expand
Remarkable adsorption capacity of CuCl2-loaded porous vanadium benzenedicarboxylate for benzothiophene.
TLDR
This work has shown the remarkable adsorption capacity for BT over a modified MOF, CuCl2-loaded MIL47 (MIL = materials of the Institute Lavoisier), and the contribution of loaded CuCl 2 to the adsorptive removal of BT. Expand
Dynamics of removal of organosulfur compounds from diesel by adsorption on carbon aerogels for fuel cell applications
Carbon aerogels (CAs) were investigated as adsorbents for the desulfurization of liquid hydrocarbon fuels for fuel cell applications. Synthetic mixtures of dibenzothiophene (DBT) and… Expand
...
1
2
3
4
5
...