Adsorption of two gas molecules at a single metal site in a metal-organic framework.

Abstract

One strategy to markedly increase the gas storage capacity of metal-organic frameworks is to introduce coordinatively-unsaturated metal centers capable of binding multiple gas molecules. Herein, we provide an initial demonstration that a single metal site within a framework can support the terminal coordination of two gas molecules-specifically hydrogen, methane, or carbon dioxide.

DOI: 10.1039/c6cc02494g

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Cite this paper

@article{Runevski2016AdsorptionOT, title={Adsorption of two gas molecules at a single metal site in a metal-organic framework.}, author={Tom{\vc}e Run{\vc}evski and Matthew T Kapelewski and Rodolfo M Torres-Gavosto and Jacob D Tarver and Craig M Brown and Jeffrey R. Long}, journal={Chemical communications}, year={2016}, volume={52 53}, pages={8251-4} }