# Adsorption of large ions from an electrolyte solution: a modified Poisson–Boltzmann equation

@article{Borukhov1999AdsorptionOL, title={Adsorption of large ions from an electrolyte solution: a modified Poisson–Boltzmann equation}, author={Itamar Borukhov and David Andelman and Henri Orland}, journal={Electrochimica Acta}, year={1999}, volume={46}, pages={221-229} }

## 95 Citations

### Ionic Size Effect on the Double Layer Properties: A Modified Poisson-Boltzmann Theory

- Materials Science
- 2010

On the basis of a simple modified Poisson-Boltzmann (SMPB) theory, taking into account the finite ionic size, the analytic expression for the effect of ionic size on the diffuse layer potential drop…

### Electrical double layer around a spherical colloid particle: the excluded volume effect.

- PhysicsJournal of colloid and interface science
- 2007

### Steric effects in the dynamics of electrolytes at large applied voltages. I. Double-layer charging.

- PhysicsPhysical review. E, Statistical, nonlinear, and soft matter physics
- 2007

This two-part series considers steric effects on diffuse charge dynamics (in the absence of electro-osmotic flow) and two simple models for the charging of a thin double layer, which must form a condensed layer of close-packed ions near the surface at high voltage.

### Competitive adsorption and ordered packing of counterions near highly charged surfaces: From mean-field theory to Monte Carlo simulations.

- PhysicsPhysical review. E, Statistical, nonlinear, and soft matter physics
- 2012

This work provides a better understanding of competitive adsorption of counterions of multiple species to charged surfaces and calls for further studies on the ionic size effect with application to large-scale biomolecular modeling.

### Osmotic pressure of charged colloidal suspensions: a unified approach to linearized Poisson-Boltzmann theory.

- BiologyPhysical review. E, Statistical, nonlinear, and soft matter physics
- 2002

It is shown that whether or not linear theory predicts a phase separation depends crucially on the precise definition of the pressure, showing that depending on the choice, an artificial phase separation in systems as important as DNA in physiological salt solution may result.

### Comparison of exclusion volume corrections to the Poisson-Boltzmann equation for inhomogeneous electrolytes.

- PhysicsJournal of colloid and interface science
- 2009

### Analytical Interfacial Layer Model for the Capacitance and Electrokinetics of Charged Aqueous Interfaces.

- PhysicsLangmuir : the ACS journal of surfaces and colloids
- 2018

An analytical model is constructed to account for the influence of the subnanometer-wide interfacial layer on the differential capacitance and the electro-osmotic mobility of solid-electrolyte interfaces, showing that a finite-viscosity layer explains the experimental data better than the usual hydrodynamic slip boundary condition.

### Poisson–Boltzmann for oppositely charged bodies: an explicit derivation

- Physics
- 2009

The interaction between two parallel charged plates in ionic solution is a general starting point for studying colloidal complexes. An intuitive expression of the pressure exerted on the plates is…

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