Adsorption and Oxidation of Aromatic Amines on Metal ( II ) Hexacyanocobaltate ( III ) Complexes : Implication for Oligomerization of Exotic Aromatic Compounds

Abstract

Based on the hypothesis on the presence of double metal cyanides in the primordial oceans, a series of nano-sized metal(II) hexacyanocobaltate(III) (MHCCo) with the general formula: M3[Co(CN)6]2·xH2O (where M = Zn, Fe, Ni and Mn) has been synthesized. Surface interaction of aromatic amines, namely aniline, 4-chloroaniline, 4-methylaniline and 4… (More)

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