Adducts of nickel(II) acetylacetonate chelating with heterocyclic bases: 3-cyanopyridine and 4-cyanopyridine

Zukerman-Schpector; Trindade; Dunstan

DOI:10.1107/S0108270100004662

Corpus ID: 36680281

Adducts of nickel(II) acetylacetonate chelating with heterocyclic bases: 3-cyanopyridine and 4-cyanopyridine

@article{ZukermanSchpector2000AdductsON,
  title={Adducts of nickel(II) acetylacetonate chelating with heterocyclic bases: 3-cyanopyridine and 4-cyanopyridine},
  author={Zukerman-Schpector and Trindade and Dunstan},
  journal={Acta crystallographica. Section C, Crystal structure communications},
  year={2000},
  volume={56 (Pt 7)},
  pages={
          763-5
        }
}

Zukerman-Schpector, Trindade, Dunstan

Published 2000

Chemistry, Medicine

Acta crystallographica. Section C, Crystal structure communications

In both title compounds, (acetylacetonato-O,O′)bis(3-cyanopyridine-N)nickel(II), (I), and (acetylacetonato-O,O′)bis(4-cyanopyridine-N)nickel(II), (II), both [Ni(C5H7O2)2(C6H4N2)2], the NiII atom, which is situated on a centre of symmetry, is octahedrally coordinated. Distances and angles for (I) and (II), respectively, are: Ni—O 2.009 (2)/2.016 (2) and 2.0110 (16)/2.0238 (18) A, Ni—N 2.116 (3) and 2.179 (2) A, O—Ni—O 91.86 (10) and 90.19 (7)°, and O—Ni—N 91.27 (11)/90.19 (11) and 89.65… CONTINUE READING

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