Additive effects in the palladium-catalyzed carboiodination of chiral N-allyl carboxamides.

Abstract

The use of Pd catalysis as a means to synthesize organic halides has recently received increased attention. Among the reported methods is the Pd-catalyzed carboiodination, which uses extremely bulky ligands to facilitate carbon-halogen reductive elimination from Pd(II) as the key catalytic step. When approaching substrates exhibiting low stereoselectivity… (More)
DOI: 10.1002/anie.201404007

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