Addition of diphenylacetylene to MoO(2)S(2)(2-) in NH(3)-CH(3)OH medium.

@article{Dessapt2001AdditionOD,
  title={Addition of diphenylacetylene to MoO(2)S(2)(2-) in NH(3)-CH(3)OH medium.},
  author={R{\'e}mi Dessapt and Corine Simonnet-J{\'e}gat and Jérôme Marrot and Francis Sécheresse},
  journal={Inorganic chemistry},
  year={2001},
  volume={40 16},
  pages={
          4072-4
        }
}
The reaction of MoO2S22- with diphenylacetylene in a methanol ammonia solution gives the novel dianion [Mo2(O)2(μ-S)2(η2-S2)(η2-S2C2(C6H5)2)]2- characterized by X-ray diffraction, 1H and 13C NMR. A comparison of the addition of different alkynes to oxothiomolybdates is discussed.