Acyclic diene metathesis with a monomer from renewable resources: control of molecular weight and one-step preparation of block copolymers.

@article{Rybak2008AcyclicDM,
  title={Acyclic diene metathesis with a monomer from renewable resources: control of molecular weight and one-step preparation of block copolymers.},
  author={A. Rybak and M. Meier},
  journal={ChemSusChem},
  year={2008},
  volume={1 6},
  pages={
          542-7
        }
}
The preparation of a long-chain aliphatic alpha,omega-diene from plant oil derivatives and its subsequent polymerization through acyclic diene metathesis (ADMET) is described. The ADMET bulk polymerization of the thus-obtained monomer, undecyl undecenoate, was investigated and optimized by applying ruthenium-based metathesis catalysts from Grubbs and Hoveyda-Grubbs, leading to high-molecular-weight polyesters. Moreover, by applying different amounts of methyl 10-undecenoate as a chain stopper… Expand
...
1
2
3
4
5
...

References

SHOWING 1-10 OF 34 REFERENCES
Recent advances in ADMET polymerization
...
1
2
3
4
...