Acid promoted transformations of fluorescent luminarosine and its 2'-modified analogues.

@article{Burdzy1998AcidPT,
  title={Acid promoted transformations of fluorescent luminarosine and its 2'-modified analogues.},
  author={A. Burdzy and B. Skalski and S. Paszyc and M. Popenda and R. Adamiak},
  journal={Acta biochimica Polonica},
  year={1998},
  volume={45 4},
  pages={
          941-8
        }
}
The susceptibility of highly fluorescent luminarine nucleosides to acid promoted anomerization reactions has been studied in order to select a derivative with suitable properties for chemical synthesis of luminarine-labeled oligo(deoxy)ribonucleotides. Both O-acetylated derivatives Ia-c and parent luminarosine IIa, as well as 2'-O-methylluminarosine IIb, and 2'-deoxyluminarosine IIc undergo anomerization at pH = 4 however, at considerably different velocities. In the case of O-protected… Expand
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Photocycloaddition of the T1 excited state of thioinosine to uridine and adenosine.
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