Acid promoted transformations of fluorescent luminarosine and its 2'-modified analogues.
@article{Burdzy1998AcidPT, title={Acid promoted transformations of fluorescent luminarosine and its 2'-modified analogues.}, author={A. Burdzy and B. Skalski and S. Paszyc and M. Popenda and R. Adamiak}, journal={Acta biochimica Polonica}, year={1998}, volume={45 4}, pages={ 941-8 } }
The susceptibility of highly fluorescent luminarine nucleosides to acid promoted anomerization reactions has been studied in order to select a derivative with suitable properties for chemical synthesis of luminarine-labeled oligo(deoxy)ribonucleotides. Both O-acetylated derivatives Ia-c and parent luminarosine IIa, as well as 2'-O-methylluminarosine IIb, and 2'-deoxyluminarosine IIc undergo anomerization at pH = 4 however, at considerably different velocities. In the case of O-protected… Expand
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