Acid of Krypton and Its Barium Salt

  title={Acid of Krypton and Its Barium Salt},
  author={Alex G. Streng and Aristid v. Grosse},
  pages={242 - 243}
An acid of krypton is formed when krypton tetrafluoride is slowly hydrolyzed by ice at —30� to —60�C. The yield is 2 to 3 percent (mole). A barium salt of this acid, thermally stable at room temperature, is formed by the hydrolysis of krypton tetrafluoride with a 0.35N solution of barium hydroxide at O� to 5�C in a yield of approximately 7 percent by weight. 
16 Citations
Electronic Structures of Kryptates and Xenates
THE recent preparation of kryptates1 and xenates2 by Grosse et al. opens a new chapter in rare-gas chemistry. Up to now the compounds that have been made have presented no new problems in chemical
Structural Chemistry of Fluorides and Oxide Fluorides of Nonmetals
The structural features of the nonmetal fluorides and oxide fluorides can now be explained and useful predictions can be made. The same applies in part to the chemistry of this class of compounds.
The inert gases, or noble gases as they are now more appropriately called, are a remarkable group of elements. The lightest, helium, was recognized in t he gases of the sun before it was isolated on
Strukturchemie von Fluoriden und Oxidfluoriden der Nichtmetalle
Das Strukturverhalten der Nichtmetallfluoride und -oxidfluoride ergibt heute ein einheitliches Bild. Das gleiche gilt daher zum Teil auch fur die Chemie dieser Verbindungen. Aussagen uber das
Edelgasverbindungen mit dem Liganden –OTeF5
Die Verbindungen Xe(OTeF5)4, Xe(OTeF5)6, OXe(OTeF5)4 sowie gemischt substituierte Derivate OXeFx(OTeF5)4−x werden beschrieben und im Zusammenhang mit den alteren Verbindungen Xe(OTeF5)2 und
What's in a Name?—A Short History of Coordination Chemistry from Then to Now
This article traces the development of coordination chemistry and shows how progress in the science has been paralleled by the development of a vocabulary and nomenclature to describe new concepts,
Die Chemie der Edelgase
Vor fast genau funfzig Jahren hat W. Kossel seine weittragende, auch heute noch nicht wesentlich eingeschrankte Idee von der besonderen Stabilitat abgeschlossener Elektronenkonfigurationen
The use of synthetic forms in preservation and exploitation of the gene pool of wild common wheat relatives
The results of investigation and exploitation of the synthetic genome-added form Triticum miguschovae and genome-substituted forms Avrodes, Avrosis, Avrolata, Avrotata,Avroale, and Avrocum are reported.
Edelgase: Elemente der achten Hauptgruppe


Xenon Tetrafluoride: Reaction with Aqueous Solutions
Xenon tetrafluoride reacts with water to yield xenon, oxygen, hydrofluoric acid, and a very soluble species containing Xenon, which is identified as xenon (VI) oxide, XeO3.
Geometry of the Perxenate Ion
A three-dimensional x-ray analylsis of a crystallinie solid of Xe+8 formed by the reaction of XeF6 with sodium hydroxide solution indicates that it is sodium perxenate octahydrate, Na4XeO6 * 8H2O.
Fluorine Compounds of Xenon and Radon
The heaviest "inert gas," radon, also reacts with fluorine, yielding a compound less volatile than xenon tetrafluoride.