Access to Six- and Seven-Membered 1,7-Fused Indolines via Rh(III)-Catalyzed Redox-Neutral C7-Selective C-H Functionalization of Indolines with Alkynes and Alkenes.

Abstract

We report herein a new strategy for the Rh(III)-catalyzed redox-neutral C7-selective C-H activation/annulation of indolines to rapidly access various privileged 1,7-fused indolines by utilizing an oxidizing-directing group. For example, a Rh(III)-catalyzed redox-neutral C7-selective C-H functionalization of indolines with arylalkynes is described to… (More)
DOI: 10.1021/acs.joc.5b00684

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@article{Wang2015AccessTS, title={Access to Six- and Seven-Membered 1,7-Fused Indolines via Rh(III)-Catalyzed Redox-Neutral C7-Selective C-H Functionalization of Indolines with Alkynes and Alkenes.}, author={Xuan Wang and Huanyu Tang and Huijin Feng and Yuanchao Li and Yaxi Yang and Bing Zhou}, journal={The Journal of organic chemistry}, year={2015}, volume={80 12}, pages={6238-49} }