Absolute configurations of fungal and plant metabolites by chiroptical methods. ORD, ECD, and VCD studies on phyllostin, scytolide, and oxysporone.

@article{Mazzeo2013AbsoluteCO,
  title={Absolute configurations of fungal and plant metabolites by chiroptical methods. ORD, ECD, and VCD studies on phyllostin, scytolide, and oxysporone.},
  author={Giuseppe Mazzeo and Ernesto Santoro and Anna Andolfi and Alessio Cimmino and Pavle Troselj and Ana G. Petrovic and Stefano Superchi and Antonio Evidente and Nina D Berova},
  journal={Journal of natural products},
  year={2013},
  volume={76 4},
  pages={588-99}
}
The absolute configuration (AC) of the bioactive metabolites phyllostin (1) and scytolide (2), two hexahydro-1,4-benzodioxines produced by Phyllosticta cirsii, and oxysporone (3), a dihydrofuropyranone recently isolated from a strain of Diplodia africana, has been assigned by computational analysis of their optical rotatory dispersion (ORD), electronic circular dichroism (ECD), and vibrational circular dichroism (VCD) spectra. Computational prediction of ORD, ECD, and VCD allowed us to assign… CONTINUE READING
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