Absolute configuration determination of chiral molecules in the solution state using vibrational circular dichroism.

@article{Freedman2003AbsoluteCD,
  title={Absolute configuration determination of chiral molecules in the solution state using vibrational circular dichroism.},
  author={Teresa B N Freedman and Xiaolin Cao and Rina K. Dukor and Laurence A. Nafie},
  journal={Chirality},
  year={2003},
  volume={15 9},
  pages={743-58}
}
Advances in the measurement, calculation, and application of vibrational circular dichroism (VCD) for the determination of absolute configuration are described. The purpose of the review is to provide an up-to-date perspective on the capability of VCD to solve problems of absolute stereochemistry for chiral molecules primarily in the solution state. The scope of the article covers the experimental methods needed for the accurate measurement of VCD spectra and the theoretical steps required to… CONTINUE READING

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